Coordination of lanthanide acetates
نویسندگان
چکیده
منابع مشابه
Fabrication of lanthanide oxide microspheres and hollow spheres by thermolysis of pre-molding lanthanide coordination compounds.
A series of lanthanide oxide microspheres and hollow spheres have been fabricated by thermolysis of corresponding lanthanide coordination compounds formed via bottom-up self-assembly.
متن کاملBiological and Clinical Aspects of Lanthanide Coordination Compounds
The coordinating chemistry of lanthanides, relevant to the biological, biochemical and medical aspects, makes a significant contribution to understanding the basis of application of lanthanides, particularly in biological and medical systems. The importance of the applications of lanthanides, as an excellent diagnostic and prognostic probe in clinical diagnostics, and an anticancer material, is...
متن کاملSyntheses, structures, and photoluminescence of 1-D lanthanide coordination polymers.
Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H(2)L and H(2)L' (H(2)L = N,N(1)-ethylene bis(salicylideneimine); H(2)L' = N,N(1)-bis(3-methoxysalicylidene)ethylene-1,2-diamine). The polymeric structures are formed by bridging neutral H(2)L units in the case of {[Ln(2)L(2)(CF(3)SO(3))(H(2)L)(4)(MeOH)] x CF(3)SO(3)}(n) (Ln ...
متن کاملFine-tuning of lanthanide-monocarboxylate coordination networks through ligand decoration.
We report herein five new coordination polymers of general formula [LnNa(C(6)H(5)CO(2))(4)] where Ln = Y (6), Tb (7), Er (8), [DyNa(CH(3)CO(2))(4)(MeOH)] (9) and [DyNa(C(3)H(7)CO(2))(4)] (10). Single crystal structure analyses revealed that all compounds have a repeating unit containing one Ln(3+), one Na(+) and four monocarboxylate ligands (RCO(2)(-)) (R = -CH(3), -C(3)H(7), -C(6)H(5)). Compou...
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The synthesis of hexanuclear lanthanide hydroxo complexes by controlled hydrolysis led to polymorphic compounds. The hexanuclear entities crystallize in four different ways that depend on the extent of their hydration. The four structures can be described as hexanuclear lanthanide entities with formula [Ln(6)(mu(6)-O)(mu(3)-OH)(8)(NO(3))(6)(H(2)O)(12)](2+). Two additional NO(3)(-) ions intercal...
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ژورنال
عنوان ژورنال: Journal of Inorganic and Nuclear Chemistry
سال: 1969
ISSN: 0022-1902
DOI: 10.1016/0022-1902(69)80198-3